Hello David. You are completely right that baking is a science of precise chemical reactions, and substituting a liquid sweetener like agave nectar for granulated sugar requires a few specific adjustments to keep your cake's crumb, moisture, and structure intact.
1. Sweetener Ratio:
Agave nectar is sweeter and more concentrated than granulated white sugar. A reliable rule of thumb is to use 2/3 cup of agave nectar for every 1 cup of granulated sugar called for in the recipe. If your recipe is already quite sweet, you can reduce this to 1/2 cup.
2. Liquid Compensation:
Because agave introduces extra moisture, you need to reduce the other liquids in your batter (such as milk, water, or buttermilk) by approximately 1/4 cup (4 tablespoons) for every 1 cup of agave used. If the recipe has little to no liquid ingredients, you can alternatively add 1 to 2 tablespoons of flour to balance the hydration.
3. Temperature Adjustment for Air Fryers:
Agave nectar contains a high proportion of fructose, which caramelizes and browns at a significantly lower temperature than sucrose. In standard baking, you should reduce the oven temperature by 25 degrees Fahrenheit (around 15 degrees Celsius). In an air fryer, where convective airflow is much more intense, this step is essential to prevent the top and edges from scorching before the middle bakes through. Set your air fryer 25 to 30 degrees Fahrenheit lower than what the standard recipe recommends, and monitor the cake closely near the end of the cooking time.
I hope these adjustments help you achieve a well-structured and delicious result in your air fryer. Happy baking!