Hello there! That is a very valid question, and there is actually a wonderful mix of culinary tradition, sensory balance, and physiological mechanics behind this pairing.
In Russian food culture, pickles belong to the ritual of 'zakuski', which are cold savory appetizers consumed immediately after taking a shot of chilled vodka. When you drink a strong spirit, the high concentration of ethanol stimulates thermal pain receptors in your mouth and throat, leading to the sharp burning sensation and a temporary drying out of the oral mucosa.
A crisp pickle acts as a precise culinary counterweight. Traditional Russian pickles are typically lacto-fermented in a brine of water, salt, garlic, and dill, rather than heavily preserved in sharp white vinegar. The high salinity combined with the mellow sourness of lactic acid immediately stimulates your salivary glands. This rapid rush of saliva coats your palate and throat, cutting straight through the ethanol aftertaste and extinguishing the burn almost instantly.
Furthermore, there is a physiological benefit to the practice. Alcohol inhibits antidiuretic hormone production, leading to fluid and electrolyte loss. Taking in salt, water, and trace minerals from pickles and brine helps mitigate this effect and prepares the stomach for digestion, which is why fermented foods have historically accompanied heavy feasts across Eastern Europe.
So while it began as an intuitive cultural custom, the science of taste contrast and mucosal protection makes it an exceptionally functional pairing.