Shrimp shrink during boiling due to the physical and chemical changes in their muscle structure. Shrimp meat is composed of water, protein, and connective tissue. When heat is applied, the proteins denature and contract tightly, squeezing out the water trapped within the muscle fibers. Furthermore, commercial frozen shrimp often contain an ice glaze applied to prevent dehydration in storage; this glaze melts immediately, adding to the perceived shrinkage. To minimize this, do not overboil them. Remove the shrimp as soon as they turn pink and opaque, usually within two to three minutes, to retain moisture and size.